You can see all invoices in your Inbox that do not have an approval setup applied. To see this report,
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When in Expense Management main menu, go to Invoice Lifecycle and select 0- Config.
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Click on Approvals .
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Click on the Approvers Pending Definition tab.
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Click on the value populated under the Qty column.
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A pop-up window will display the account information for the invoice. You can use this information to add a New user setup for this account.